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1-Bromo-3,3,3-trifluoroacetone 1-溴-3,3,3-三氟丙酮

规格: 95%

CAS: 431-35-6

产品编号: H34536

MDL: MFCD00039237

品牌: INFI

Chemical Name	1-Bromo-3,3,3-Trifluoroacetone
CAS Number	431-35-6
Alfabeta Name	BROMOTRIFLUOROACETONE 3111---,,
MDL Number	MFCD00039237
PubChem Substance ID	87564176
EC Number	207-071-9
Beilstein Registry Number	1703387
Synonym	3-Bromo-1,1,1-trifluoropropan-2-one {LY} 3-Bromo-1,1,1-trifluoropropan-2-one {} {LY} 3-Bromo-1,1,1-trifluoropropan-2-one {} {} {LY} 3-Bromo-1,1,1-trifluoropropan-2-one {} {} {} {LY} 3-Bromo-1,1,1-trifluoropropan-2-one {} {} {} {} {LY} 3-Bromo-1,1,1-trifluoropropan-2-one {} {} {} {} {} {LY} 3-Bromo-1,1,1-trifluoropropan-2-one {} {} {} {} {} {} {LY} 3-Bromo-1,1,1-trifluoropropan-2-one {} {} {} {} {} {} {} {LY} 3-Bromo-1,1,1-trifluoropropan-2-one {} {} {} {} {} {} {} {} {LY} 3-Bromo-1,1,1-trifluoropropan-2-one {} {} {} {} {} {} {} {} {} {LY} 3-Bromo-1,1,1-trifluoropropan-2-one {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 3-Bromo-1,1,1-trifluoropropan-2-one {} {} {} {} {} {} {} {} {} {} {} {LY} 3-Bromo-1,1,1-trifluoropropan-2-one {} {} {} {} {} {} {} {} {} {} {} {} {LY} 3-Bromo-1,1,1-trifluoropropan-2-one {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 3-Bromo-1,1,1-trifluoropropan-2-one {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 3-Bromo-1,1,1-tri
Chemical Name Translation	3-溴-1,1,1-三氟丙酮
Reaxys-RN	1703387
InChIKey	ONZQYZKCUHFORE-UHFFFAOYSA-N
LabNetwork Molecule ID	LN00116183
InChI	InChI=1S/C3H2BrF3O/c4-1-2(8)3(5,6)7/h1H2
Canonical SMILES	O=C(CBr)C(F)(F)F

GHS Symbol

Warnings	LACHRYMATOR, FLAMMABLE, CORROSIVE
WGK Germany	3
Hazard statements
H225 Highly flammable liquid and vapour 高度易燃液体和蒸气 H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
Personal Protective Equipment	Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Hazard Codes	F,C
Precautionary statements
P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。 P233 Keep container tightly closed. ?保持容器密闭。 P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。 P241+P242+P243 P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。 P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。 P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。 P301+P330+P331+P310 P303+P361+P353 P303+P361+P353+P310+P363 P304+P340 P304+P340+P310 P305+P351+P338 P305+P351+P338+P310 P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。 P403+P235 P405 Store locked up. 上锁保管。 P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word
Packing Group	II
UN Number	2924 UN2924
Risk Statements
R11 Highly flammable 非常易燃 R37 Irritating to respiratory system 刺激呼吸道 R34 Causes burns 会导致灼伤
Safety Statements
S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见； S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护； S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）； S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
Hazard Class	3/8
Storage condition	2-8°C, stored under nitrogen {LY} 2-8°C, stored under nitrogen {} {LY} 2-8°C, stored under nitrogen {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {

{SA}

Beil. 1 ,IV,3220

{SA}

FT-NMR 1 (1), 652:B / RegBook 1 (1), 459:B / Structure Index 1 , 65:A:6

{ALF} A novel reductive olefination reaction with aldehydes, mediated by Ti(O-i-Pr)4 and PPh3, provides a one-pot synthesis of trifluoromethylated trans-allylic alcohols: Chem. Commun., 2195 (1998):

{ALF}

{ALF} The oxime is readily converted with base to the highly reactive species 1,1,1-trifluoro-2-nitroso-2-propene, which undergoes hetero-Diels-Alder reactions, e.g. with cyclopentadiene or indole to give fused oxazolines. The indole adduct rearomatizes to give 1-(3-indolyl)-3,3,3-trifluoroacetoxime: J. Org. Chem., 57, 339 (1992).

431-35-6 H34536 1-Bromo-3,3,3-trifluoroacetone 1-溴-3,3,3-三氟丙酮

化学属性

Mol. Formula	C3H2BrF3O
Mol. Weight	190.95
Boiling Point	87 °C at 743 mmHg
Refractive index	1.3730 to 1.3770
Density	1.839
Flash Point	5°C
TSCA	No
Melting Point	<-80 °C
Appearance	colorless liq.

*以上化合物性质及应用等信息仅供参考

手性催化剂及配体

合成砌块

医药中间体

1-Bromo-3,3,3-trifluoroacetone 1-溴-3,3,3-三氟丙酮

规格: 95%

化学属性

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